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Sunday, April 7, 2013
The chemical properties of 2-Amino-3-nitropyridine
2-Amino-3-nitropyridine as a anemic chicken solid. Soluble in water, alcohol, ether, etc. A lot of amoebic solvents. The pyridine hydro miscible in any proportion, while abandoning the a lot of arctic and non-polar amoebic compounds, assertive asleep salts can be attenuated even. Pyridine is a bread-and-butter broadly acclimated value. Pyridine molecules with top baptize solubility affidavit in accession to the atom accepting a beyond polarity, but aswell because of the pyridine nitrogen atom distinct electron brace can with baptize to anatomy hydrogen bonds. Pyridine anatomy hydrocarbyl accomplish it a ample affection of amoebic molecules, so arctic or non-polar amoebic admixture may be dissolved. On the nitrogen atom distinct electron brace able to anatomy complexes with metal ions such as Ag, Ni, Cu, etc., which after-effects in that it can deliquesce the asleep salts. Forms an azeotropic admixture with water, the baking point of 92 to 93 ° C. Pyridine and its derivatives, benzene stability, agnate to its acuteness with nitrobenzene. Typical ambrosial electrophilic barter acknowledgment takes abode in the 3,5-position, but the acknowledgment is lower than that of benzene, nitration, halogenation, sulfonation acknowledgment is about beneath prone. Pyridine is a anemic tertiary amine, to anatomy water-insoluble salts with a array of acids (such as picric acerbic or perchloric acid, etc.) in an booze solution. The automated use of pyridine absolute about 1% of 2 - methyl-pyridine, can be use as the aberration of the attributes of salt, amid it and its homologues. Pyridine is aswell accessible with a array of metal ions to anatomy apparent complexes. Pyridin than benzene is simple to restore and restore Hexahydropyridine, such as the role of the brownish sodium and booze (or piperidine). Pyridine and hydrogen peroxide, and affected to blaze of the pyridine N-oxide.
2-Amino-3-nitropyridine in accession to as a solvent, pyridine in the industry can aswell be acclimated as a denaturant, advice agent, as able-bodied as the amalgam of a alternation of articles (including medicines, disinfectants, dyes, aliment seasonings, adhesives, explosives etc.) of the starting material. Pyridine can aswell be acclimated as a catalyst, but the bulk can not be too much, or affect the artefact quality. Acclimated as a bane inhibitor, pyridine metal adjoin corrosion, the adsorption of bane inhibition. Pyridine can be acquired from accustomed atramentous tar, but aswell by acetaldehyde and ammonia obtained. Pyridine and its derivatives can aswell be actinic by a array of methods, one of the a lot of broadly Han odd pyridine synthesis, with two molecules of the beta-carbonyl compounds, such as ethyl acetoacetate and one atom of acetaldehyde abstract artefact again with a allotment of ethyl acetoacetate and ammonia formed by abstract of the dihydropyridine compound, dehydrogenation and again with an acerbic abettor (such as nitrous acid), and again anatomize carboxymethylcellulose accident to access the pyridine derivative. Aswell accessible acetylene, ammonia and booze at 500 ° C through a agitator preparation. Many derivatives of pyridine is important drugs, some of which are an important allotment of the vitamins or enzymes. The pyridine derivatives Isoniazid is an anti-TB drugs, and 2 - methyl-5 - vinylpyridine is a raw actual of constructed rubber. This artefact is flammable, with a able irritant. Its breath and air can anatomy atomic mixtures case of fire, access agitation burns easily. Reacts berserk with oxidants. Decomposition at top temperatures, the absolution of baneful nitrogen oxide gases. Violent acknowledgment with sulfuric acid, nitric acid, chromic acid, angry sulfuric acid, chlorosulfonic acid, maleic anhydride, perchloric acerbic argent access hazard. The breeze amount is too fast, simple and accession of changeless electricity. Its breath is added than air, can lower the advance of ample bounded and met the blaze will blaze back.
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