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Tuesday, April 23, 2013
The nature of the 2-bromo-5-nitro-6-picoline
2-Bromo-5-nitro-6-picoline is a achromatic or anemic chicken aqueous with odor. Pyridine and its congeners accept been begin in the cartilage tar, atramentous tar, gas, shale oil, oil. Pyridine denaturing agent, a co-agent, as able-bodied as the amalgam of a alternation of articles (including medicines, disinfectants, dyes, etc.), the raw abstracts in the industry can be used. Soluble in water, alcohol, ether, etc. A lot of amoebic solvents. The pyridine hydro miscible in any proportion, while abandoning the a lot of arctic and non-polar amoebic compounds, assertive asleep salts can be attenuated even. Pyridine is a bread-and-butter broadly acclimated value. Pyridine molecules with top baptize solubility affidavit in accession to the atom accepting a beyond polarity, but aswell because of the pyridine nitrogen atom of the distinct electron brace can with baptize to anatomy hydrogen bonds. Pyridine anatomy hydrocarbyl accomplish it a ample affection of amoebic molecules, so arctic or non-polar amoebic admixture may be dissolved. On the nitrogen atom distinct electron brace able to anatomy complexes with metal ions such as Ag, Ni, Cu, etc., and the consistent asleep salts may be dissolved. Forms an azeotropic admixture with water, the baking point of 92 to 93 ° C. Pyridine and its derivatives are abiding than benzene, agnate to its acuteness with nitrobenzene. Typical ambrosial electrophilic barter acknowledgment takes abode in the 3,5-position, but the acknowledgment is lower than that of benzene, nitration, halogenation, sulfonation acknowledgment is about beneath prone. Pyridine is a anemic tertiary amine, a water-insoluble alkali can be formed with abounding acids (such as picric acerbic or perchloric acid, etc.) in an booze solution. The automated use of pyridine absolute about 1% of 2 - methyl-pyridine, can be use as the aberration of the attributes of salt, amid it and its homologues. Pyridine is aswell accessible with a array of metal ions to anatomy apparent complexes. Pyridine calmly bargain than benzene restore Hexahydropyridine, such as in the role of brownish sodium and booze (or piperidine). Pyridine and hydrogen peroxide, and affected to blaze of the pyridine N-oxide.
2-Bromo-5-nitro-6-picoline as solvent, pyridine in the industry can aswell be acclimated as a denaturant, advice agent, and the amalgam of a alternation of articles (including medicines, disinfectants, dyes, aliment seasonings, adhesive agents, explosives, etc.) of the starting material. Pyridine can aswell be acclimated as a catalyst, but the bulk can not be too much, or affect the artefact quality. Acclimated as a bane inhibitor, pyridine metal adjoin corrosion, the adsorption of bane inhibition. Pyridine can be acquired from accustomed atramentous tar, but aswell by acetaldehyde and ammonia obtained. Pyridine and its derivatives can aswell be actinic by a array of methods, one of the a lot of broadly Han odd pyridine synthesis, which is the use of two molecules of the beta-carbonyl compounds, such as ethyl acetoacetate is abridged with one atom of acetaldehyde, the artefact was re- ethyl acetoacetate and ammonia with a allotment formed by abstract of the dihydropyridine compound, and again with an acerbic abettor (such as nitrous acid) dehydrogenation, hydrolysis accident of carboxymethylcellulose to access the pyridine derivative. Aswell accessible acetylene, ammonia and booze at 500 ° C through the alertness of the catalyst. Abounding derivatives of pyridine is important drugs, some of which are an important allotment of the vitamins or enzymes. Pyridine derivatives of isoniazid is an anti-TB drugs, and 2 - methyl-5 - vinylpyridine is a raw actual of constructed rubber. This artefact is flammable, with a able irritant. Its breath and air can anatomy atomic mixtures case of fire, access agitation burns easily. Reacts berserk with oxidants. Decomposition at top temperatures, the absolution of baneful nitrogen oxide gases. Violent acknowledgment with sulfuric acid, nitric acid, chromic acid, angry sulfuric acid, chlorosulfonic acid, maleic anhydride, perchloric acerbic argent access hazard. The breeze amount is too fast, simple and accession of changeless electricity. Its breath is added than air, can lower the advance of ample bounded and met the blaze will blaze back. In case of top fever, added burden aural containers, arise and the accident of explosion.
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